![]() The knowledge of mineral acids such as hydrochloric acid would be of key importance to seventeenth-century chemists like Daniel Sennert (1572–1637) and Robert Boyle (1627–1691), who used their capability to rapidly dissolve metals in their demonstrations of the composite nature of bodies. Thus, recipes for the production of hydrochloric acid only appear in the late sixteenth century, the earliest being found in Giovanni Battista Della Porta's (1535–1615) Magiae naturalis ("Natural Magic") and in the works of other contemporary chemists like Andreas Libavius (c. However, the production of hydrochloric acid itself (i.e., as an isolated substance rather than as already mixed with nitric acid) depended on the use of more efficient cooling apparatus, which would only develop in subsequent centuries. 1300), where aqua regia was prepared by adding ammonium chloride to nitric acid. This was first described in pseudo-Geber's De inventione veritatis ("On the Discovery of Truth", after c. One important invention that resulted from the discovery of the mineral acids is aqua regia, a mixture of nitric acid and hydrochloric acid in a 1:3 proportion, capable of dissolving gold. Thirteenth-century Latin alchemists, for whom the De aluminibus et salibus was one of the main reference works, were fascinated by the chlorinating properties of corrosive sublimate, and they soon discovered that when the metals are eliminated from the process of heating vitriols, alums, and salts, strong mineral acids can directly be distilled. In this process, hydrochloric acid actually started to form, but it immediately reacted with the mercury to produce corrosive sublimate. ĭrawing on al-Razi's experiments, the De aluminibus et salibus ("On Alums and Salts"), an eleventh- or twelfth century Arabic text falsely attributed to al-Razi and translated into Latin by Gerard of Cremona (1144-1187), described the heating of metals with various salts, which in the case of mercury resulted in the production of mercury(II) chloride (corrosive sublimate). Multhauf, hydrogen chloride was produced many times without clear recognition that by dissolving it in water hydrochloric acid may be produced. ![]() However, it appears that in most of his experiments al-Razi disregarded the gaseous products, concentrating instead on the color changes that could be effected in the residue. There will distil over a strong water, which will cleave stone ( sakhr) instantly. After adding an equal weight of good crystallised Sal-ammoniac, dissolve by moisture, and distil (the mixture). Take equal parts of sweet salt, Bitter salt, Ṭabarzad salt, Andarānī salt, Indian salt, salt of Al-Qilī, and salt of Urine. In doing so, al-Razi may have stumbled upon a primitive method for producing hydrochloric acid, as perhaps manifested in the following recipe from his Kitāb al-Asrār ("The Book of Secrets"): 865–925, Latin: Rhazes) conducted experiments with sal ammoniac ( ammonium chloride) and vitriol (hydrated sulfates of various metals), which he distilled together, thus producing the gas hydrogen chloride. In the early tenth century, the Persian physician and alchemist Abu Bakr al-Razi ( c.
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